Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction     

M. Mäkelä  I. Välimäki  R. Pöykiö  H. Nurmesniemi  O. Dahl 《International Journal of Environmental Science and Technology》2013,10(6):1193-1208

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.  相似文献   

WESS: an interdisciplinary approach to catchment research     

Olaf Kolditz  Hermann Rügner  Peter Grathwohl  Peter Dietrich  Thilo Streck 《Environmental Earth Sciences》2013,69(2):313-315

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A data exploration framework for validation and setup of hydrological models   总被引：5，自引：5，他引：0  

Karsten Rink  Thomas Fischer  Benny Selle  Olaf Kolditz 《Environmental Earth Sciences》2013,69(2):469-477

Over the course of hydrological research projects often a large number of heterogeneous data sets are acquired from sources as diverse as boreholes, gauging stations or satellite imagery. This data then need to be integrated into models for the simulation of hydrological processes. We propose a framework for exploration of geoscientific data and visually guided preparation of such models. Data sets from a large number of sources can be imported, combined and validated to avoid potential problems due to artefacts or inconsistencies between data sets in a subsequent simulation. Boundary conditions and domain discretisations for surface and subsurface models can be created and tested regarding criteria indicating possible numerical instabilities. All data sets including simulation results can be integrated into a user-controlled 3D scene and aspects of the data can be enhanced using a number of established visualisation techniques including thresholding and user-defined transfer functions. We present the application of this framework for the preparation of a model for simulation of groundwater flow in a river catchment in southwest Germany investigated in the scope of the WESS project.  相似文献   

Geothermal energy systems: research perspective for domestic energy provision   总被引：1，自引：1，他引：0  

Ernst Huenges  Thomas Kohl  Olaf Kolditz  Judith Bremer  Magdalena Scheck-Wenderoth  Thomas Vienken 《Environmental Earth Sciences》2013,70(8):3927-3933

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In memory of Budagovskii Anatolii Ivanovich (1912–2008)     

Olaf Teschke  Bernd Wegner  Dirk Werner 《Water Resources》2009,36(2):240-241

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Comments on “Two-dimensional concentration distribution for mixing-controlled bioreactive transport in steady-state” by O.A. Cirpka and A.J. Valocchi     

Haibing Shao  Florian Centler  Cecilia De Biase  Martin Thullner  Olaf Kolditz 《Advances in water resources》2009

In this comment we present a re-analysis of the analytical solution presented by Cirpka and Valocchi for steady-state concentrations of dissolved bioreactive compounds and bacterial biomass in porous media. We discuss the validity range of the analytical solution. In particular, the criterion used to determine the sustainability of biomass is revisited. This re-analysis shows that the ω$\omega$ criterion used by Cirpka and Valocchi is only a necessary but not a sufficient criterion to determine the bioreactive zones. As a consequence, the analytical solution does not provide the exact distribution of compounds throughout the domain, but can serve as upper or lower boundaries for species concentrations at a given location. These conclusions are supported by the simulation results obtained from an established reactive transport model.  相似文献   

Factors affecting clarity of freshwater lakes in Brandenburg, Germany     

Jens Pfannkuche  Jens Meisel  Olaf Mietz   《Limnologica》2000,30(4):311-321

In the German State Brandenburg, water clarity and the concentrations of the water quality components chlorophyll a, seston and gelbstoff were measured in 27 lakes. Correlation analysis showed, that spectral beam attenuation at 662 and 514 nm was mainly dependent on changes in chlorophyll a concentrations. In the UV-channel at 360 nm, beam attenuation depended mostly on gelbstoff.

Multiple linear regression provided a direct model of beam attenuation at 514 nm with the inputs of inorganic seston, chlorophyll a and gelbstoff. The specific beam attenuation coefficients were comparable to other natural waters around the world. An inverse model is presented, from which gelbstoff and chlorophyll a could be predicted with some accuracy from the inputs of beam attenuation coefficients at 514 and 360 nm. However, it became obvious that biological variability put major constraints on the predictive capacity of both the direct and the inverse model.

Furthermore, we observed a good correspondence of Secchi depth and the inverse of beam attenuation at 514 nm. The predictions of Secchi depth and chlorophyll a concentration from the inverse model were assessed in perspective of using this instrument instead of laborious chemical analysis for future trophic status classification according to LAWA (Länderarbeitsgemeinschaft Wasser). Predictions of trophic status were principally good when using calibrated models, however, quality of classification critically depended on predictions of chlorophyll a.  相似文献   

An Open,Object-Based Framework for Generating Anisotropy in Sedimentary Subsurface Models     

Jeremy P. Bennett  Claus P. Haslauer  Martin Ross  Olaf A. Cirpka 《Ground water》2019,57(3):420-429

The spatial distribution of hydraulic properties in the subsurface controls groundwater flow and solute transport. However, many approaches to modeling these distributions do not produce geologically realistic results and/or do not model the anisotropy of hydraulic conductivity caused by bedding structures in sedimentary deposits. We have developed a flexible object-based package for simulating hydraulic properties in the subsurface—the Hydrogeological Virtual Realities (HyVR) simulation package. This implements a hierarchical modeling framework that takes into account geological rules about stratigraphic bounding surfaces and the geometry of specific sedimentary structures to generate realistic aquifer models, including full hydraulic-conductivity tensors. The HyVR simulation package can create outputs suitable for standard groundwater modeling tools (e.g., MODFLOW), is written in Python, an open-source programming language, and is openly available at an online repository. This paper presents an overview of the underlying modeling principles and computational methods, as well as an example simulation based on the Macrodispersion Experiment site in Columbus, Mississippi. Our simulation package can currently simulate porous media that mimic geological conceptual models in fluvial depositional environments, and that include fine-scale heterogeneity in distributed hydraulic parameter fields. The simulation results allow qualitative geological conceptual models to be converted into digital subsurface models that can be used in quantitative numerical flow-and-transport simulations, with the aim of improving our understanding of the influence of geological realism on groundwater flow and solute transport.  相似文献   

Periglacial trimlines,former nunataks and the altitude of the last ice sheet in Wester Ross,northwest Scotland     

Colin K. Ballantyne  Danny McCarroll  Atle Nesje  Svein Olaf Dahl 《第四纪科学杂志》1997,12(3):225-238

High-level weathering limits separating ice-scoured topography from frost-weathered detritus were identified on 28 mountains in Wester Ross at altitudes of 700–960 m, and a further 22 peaks support evidence of ice scouring to summit level. Weathering limits are defined most clearly on sandstone and gneiss, which have resisted frost shattering during the Late Devensian Lateglacial, but can also be distinguished on schists and quartzite. Schmidt hammer measurements and analyses of clay mineral assemblages indicate significantly more advanced rock and soil weathering above the weathering limits. The persistence of gibbsite above weathering limits indicates that they represent the upper limit of Late Devensian glacial erosion. The regular decline of weathering-limit altitudes along former flowlines eliminates the possibility that the weathering limits represent former thermal boundaries between protective cold-based and erosive warm-based ice. The weathering limits are therefore interpreted as periglacial trimlines that define the maximum surface altitude of the last ice sheet. Calculated basal shear stresses of 50–95 kPa are consistent with this interpretation. Reconstruction of ice-sheet configuration indicates that the former ice-shed lay above 900 m along the present watershed, and that the ice surface descended northwestwards, with broad depressions along major troughs and localised domes around independent centres of ice dispersal. Extrapolation of the ice surface gradient and altitude suggests that the ice sheet did not overrun the Outer Hebrides, but was confluent with the independent Outer Hebrides ice-cap in the North Minch basin. Erratics located up to 140 m above the reconstructed ice surface are inferred to have been emplaced by a pre-Late Devensian ice sheet (or ice sheets) of unknown age. © 1997 John Wiley & Sons, Ltd.  相似文献   

青海湖盆地史前狩猎采集人群的石料利用策略研究     

申旭科  王建  姚娟婷  夏欢  王倩倩  任晓燕  Olaf Joris  张东菊 《第四纪研究》2020,(2):525-537

史前人类向青藏高原扩散的过程和适应高海拔缺氧环境的机制是多学科关注的热点科学问题.青海湖盆地是青藏高原旧石器-中石器时代遗址分布最为丰富的区域,对这些遗址出土的石制品原料的分析有助于深入理解青藏高原史前狩猎采集人群的石料开发策略、人群迁徙和交流联系.青海湖盆地151遗址出土的928件石制品的石料研究分析显示,处于末次冰消期的下文化层的石制品以近源的石英和石英岩为主要原料,而处于全新世早中期的上文化层在同类型近源石料仍占主体地位的情况下,开始出现较高比例和多样化的优质硅质石料,并且主要用于生产细石器.野外调查和查阅地质资料均未发现青海湖盆地内有151遗址中出现的同类型优质硅质石料产出,推测其来自远距离搬运.青海湖盆地内其他8个末次冰消期至全新世中期遗址的3269件石制品石料分析结果显示,与151遗址同类型的远源优质硅质石料在全新世早期开始在盆地内的遗址中出现.这一结果表明青海湖盆地末次冰消期古人类活动强度和范围有限,全新世早中期古人类受到全新世大暖期气候变好和周边地区农业人群兴起挤压活动空间的双重影响,在高原上的活动范围和强度大大增加,伴随着开始有意识地开发优质石料,较频繁地进行远距离迁移和人群交流.远源优质硅质石料的产地可能位于北祁连山区和青藏高原上的陆相火山岩区,需要未来更深入的研究揭示.该研究为深入理解青藏高原古人类的高海拔环境适应策略和移动模式提供了重要材料,为理解史前人类向高原扩散的机制提供了重要信息.  相似文献